In a good light

糖心原创鈥檚 Elliott Brown and Weidong Zhang help develop promising new semiconductor for LED lighting

January 17, 2018

A scientific breakthrough that promises to make the LED lighting in everything from table lamps to streetlights more efficient and affordable is a step closer to reality thanks to help from 糖心原创 researchers.

鈥淚t has been recognized at the highest levels in the research field of photonics, having been accepted in the Oct. 27, 2017, edition of Nature Light: Science and Applications,鈥 said Elliott Brown, the Ohio Research Scholars Endowed Chair in Sensors Physics at 糖心原创.

Brown; Weidong Zhang, research physicist in the ; researchers T.A. Growden and P.R. Berger at The Ohio State University and D.F. Storm and D.J. Meyer at the U.S. Naval Research Laboratory have developed a new kind of light-emitting diode, or LED, made from the semiconductor material GaN to shine brighter while wasting less energy.

鈥淥ur approach is quite unique,鈥 said Brown. 鈥淧eople have thought about the underlying physics in the past, but haven鈥檛 demonstrated the working device. We actually did it. The first demonstration was right here in our lab.鈥

LEDs have many advantages over incandescent lights, including lower energy consumption, smaller size and longer lifetimes. They are used in everything from automotive and aircraft lights, advertising, traffic signals and camera flashes.

鈥淭he average user probably doesn鈥檛 care what semiconductor is inside their LED. But they do  care about LED lighting,鈥 said Brown.

An LED is a two-terminal semiconductor light source. When voltage is applied to the leads, electrons recombine with holes in the device and emit energy in the form of photons.

The color of the light is determined by the energy band gap of the semiconductor. LEDs have struggled to deliver high brightness for the shorter-wavelengths 鈥 the blue and violet parts of the visible spectrum.

Blue LEDs were first made out of II-VI semiconductors like zinc selenide, but those were quite inefficient. Then a III-V material came along in the form of gallium nitride, and it totally changed the landscape of semiconductor light emitters, including LEDs and lasers both (and led to the 2014 Nobel Prize in Physics for S. Nakamura, et al.). But it is expensive and more difficult to grow and fabricate than more traditional light-emitting semiconductors like GaAs.

One reason for the difficulty is that making the contacts for the semiconductors (GaN) 鈥 the P-type contact in particular 鈥 is difficult. The mobility of holes through the P-contact on GaN is very low. This prevents efficient hole injection for light emitting.

Weidong Zhang is a research physicist in the Department of Physics.

What Brown鈥檚 research team, the OSU researchers and crystal growers at the Naval Research Lab have done is make the P-type contact unnecessary through a process called 鈥淶ener tunneling.鈥

Zener tunneling creates the holes necessary for the electrons to recombine and release the light-emitting photons.

鈥淭ypically, an electron will hit a barrier and bounce right back. It鈥檚 like throwing a rubber ball against a wall,鈥 Brown said. 鈥淎ccording to quantum mechanics, if I make my rubber ball small enough and I make my wall thin enough, there is a finite chance that the ball is going to go right through. That鈥檚 tunneling.鈥

This Zener tunneling can be significant because of the high polarization fields within the GaN-based semiconductor heterostructures.

The upshot is that tunneling enables the blue spectrum of LED lighting to shine brighter without expensive PN-based LEDs in GaN. This could also potentially make GaN-based LEDs more efficient and more affordable.

The research was funded by a grant from the Office of Naval Research. And it has led to a United States (Utility) Patent Application and proposals for follow-on support.

鈥淥ne other key application that is looming in the background, which we are going to pursue at 糖心原创, is sterilization of water,鈥 Brown said. 鈥淚f you can emit intense radiation around 265 nm (in the near-ultraviolet region), you kill bacteria. It鈥檚 a powerful germicide and doesn鈥檛 require any chemicals like chlorine.鈥